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In 1999, Buffy Sanders was trapped in a cave outside Smallville that was found to contain kryptonite-infected stalactites which mutated the bats living there. After being bitten by these bats, she developed super vampiric traits and became president of Tri-Psi, passing on her powers to the members of her sorority by biting them.
After Buffy became president, the Tri-Psi became the most exclusive sorority on campus, only recruiting one girl every year. Lana Lang was a sister of Tri-Psi until the sorority was shut down and she was cured by Clark's use of a kryptonite based cure developed by LuthorCorp.